65 research outputs found
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Predicted thermochemistry and unimolecular kinetics of nitrous sulfide
Article on predicted thermochemistry and unimolecular kinetics of nitrous sulfide
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Kinetic Studies of Chlorobenzene Reactions with Hydrogen Atoms and Phenyl Radicals and the Thermochemistry of 1-Chlorocyclohexadienyl Radicals
Article on kinetic studies of chlorobenzene reactions with hydrogen atoms and phenyl radicals and the thermochemistry of 1-chlorocyclohexadienyl radicals
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Kinetic Studies of the Reaction of Atomic Chlorine with Chlorobenzene
Article on kinetic studies of the reaction of atomic chlorine with chlorobenzene
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Experimental and Computational Studies of the Kinetics of the Reaction of Hydrogen Atoms with Carbon Disulfide
Article discussing an investigation of the reaction of H + CS₂ products. The reaction was found to be pressure dependent and in the fall-off region or near the low pressure limit. Transition state theory yields an estimate for the high-pressure limit of addition over 290–300 K of 1.3 × 10−9 exp( −7.2 kJ mol −1 /RT) cm3 molecule −1 s −1. Uncertainties are discussed in the text
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Experimental and kinetic modeling study of C2H4 oxidation at high pressure
Article on an experimental and kinetic modeling study of C2H4 oxidation at high pressure
Unveiling A Core Linguistic Region in Large Language Models
Brain localization, which describes the association between specific regions
of the brain and their corresponding functions, is widely accepted in the field
of cognitive science as an objective fact. Today's large language models (LLMs)
possess human-level linguistic competence and can execute complex tasks
requiring abstract knowledge and reasoning. To deeply understand the inherent
mechanisms of intelligence emergence in LLMs, this paper conducts an analogical
research using brain localization as a prototype. We have discovered a core
region in LLMs that corresponds to linguistic competence, accounting for
approximately 1% of the total model parameters. This core region exhibits
significant dimension dependency, and perturbations to even a single parameter
on specific dimensions can lead to a loss of linguistic competence.
Furthermore, we observe that an improvement in linguistic competence does not
necessarily accompany an elevation in the model's knowledge level, which might
imply the existence of regions of domain knowledge that are dissociated from
the linguistic region. Overall, exploring the LLMs' functional regions provides
insights into the foundation of their intelligence. In the future, we will
continue to investigate knowledge regions within LLMs and the interactions
between them.Comment: Work on progres
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High-Temperature Kinetics of the Reaction between Chlorine Atoms and Hydrogen Sulfide
Article on high-temperature kinetics of the reaction between chlorine atoms and hydrogen sulfide
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Kinetic and Modeling Studies of the Reaction S + H2S
Article on kinetic and modeling studies of the reaction S + H2S
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Kinetics and Thermochemistry of the Addition of Atomic Chlorine to Acetylene
Article on the kinetics and thermochemistry of the addition of atomic chlorine to acetylene
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